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Thermodynamics: Heat, Energy & The Laws of Engines
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Thread 5 — Thermodynamics: Heat, Energy & The Laws That Power Engines 
Understanding How Heat Becomes Motion, Electricity & Work

Thermodynamics is at the core of mechanical engineering. 
Engines, power plants, refrigerators, turbines, rockets — they all rely on the laws governing heat, energy, work and efficiency.

This thread introduces the fundamental principles that every engineer must understand.



1. What Is Thermodynamics?

Thermodynamics is the study of:
• energy 
• heat 
• work 
• temperature 
• entropy 

Engineers use thermodynamics to analyse systems such as:
• car engines 
• jet turbines 
• steam boilers 
• refrigerators 
• heat pumps 
• power stations 
• rockets and space propulsion 

Thermodynamics tells us what’s possible — and what isn’t.



2. The Zeroth Law — Temperature & Thermal Equilibrium

The Zeroth Law establishes the concept of temperature.

It says:
If A is in thermal equilibrium with B, 
and B is in thermal equilibrium with C, 
then A is in thermal equilibrium with C.

This is why thermometers work.



3. First Law of Thermodynamics — Energy Cannot Be Created or Destroyed

This is the law of energy conservation.

ΔU = Q − W

Where:
• ΔU = change in internal energy 
• Q = heat added 
• W = work done by the system

Examples:
• heating a gas increases its energy 
• expanding gas (like in an engine) does work and cools 
• compressing gas (like in a pump) requires work and heats up 

The First Law explains why fuels release energy — but not how efficient the process is.



4. Second Law of Thermodynamics — Entropy & Irreversibility

The Second Law introduces entropy — the measure of disorder.

Key ideas:
• heat naturally flows from hot → cold 
• every real process wastes some energy 
• no heat engine is 100% efficient 
• entropy of the universe always increases

This is why:
• friction wastes energy 
• engines produce heat losses 
• you can’t build a perfect machine



5. Third Law of Thermodynamics — Absolute Zero

As temperature approaches absolute zero (0 Kelvin):
• entropy approaches a minimum 
• motion of particles nearly stops 
• it becomes extremely hard to remove more energy

You can get close to absolute zero — but never reach it.



6. Heat, Work & Internal Energy

Heat (Q): 
Energy transferred due to temperature difference.

Work (W): 
Energy transferred by a force acting through distance.

Internal Energy (U): 
Energy stored in molecules (motion & interactions).

Together they form the backbone of energy analysis.



7. Ideal Gases — The Simplest Useful Model

For many engineering calculations, gases are treated as ideal.

The ideal gas law:
PV = nRT

Where:
• P = pressure 
• V = volume 
• n = moles 
• R = gas constant 
• T = temperature 

Gases expand when heated → engines generate work using this principle.



8. Heat Engines — Turning Heat Into Motion

All heat engines follow the same principle:

1. Add heat to a working fluid 
2. Fluid expands 
3. Expansion pushes a piston or turbine → produces work 
4. Waste heat is removed 
5. Cycle repeats 

Examples:
• petrol engines 
• diesel engines 
• jet engines 
• steam turbines 
• nuclear power plant turbines 



9. The Carnot Cycle — The Maximum Possible Efficiency

The Carnot cycle represents a *perfect* engine with no losses.

Its efficiency:
η = 1 − (T_cold ÷ T_hot)

This formula shows:
• engines are more efficient with hotter combustion 
• cooling systems matter 
• perfect efficiency is impossible 

Real engines always perform below the Carnot limit.



10. Refrigerators & Heat Pumps — Heat Engines in Reverse

While heat engines turn heat → work, 
refrigerators do work → move heat.

They move heat from cold → hot by spending energy.

Applications:
• refrigerators 
• freezers 
• air conditioning 
• heat pumps 
• climate control systems 

Performance is measured using COP (coefficient of performance).



11. Real-World Thermodynamic Applications

Thermodynamics powers almost all modern technology:
• internal combustion engines 
• electric power generation 
• aerospace propulsion 
• industrial heating systems 
• cryogenics 
• renewable power (solar thermal, geothermal) 
• steam-based power plants 
• HVAC (heating, ventilation & air conditioning) 

Anywhere heat, work and energy interact — thermodynamics is essential.



End of Thread — Thermodynamics & Energy
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